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. 2011 Jun 28;47(24):6987-9.
doi: 10.1039/c1cc11737h. Epub 2011 May 11.

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

S M Ibrahim Al-Rafia  1 , Adam C Malcolm, Sean K Liew, Michael J Ferguson, Robert McDonald, Eric Rivard
Affiliations

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

S M Ibrahim Al-Rafia et al. Chem Commun (Camb). .

Abstract

The N-heterocyclic olefin, IPr=CH(2) (IPr = [(HCNDipp)(2)C], Dipp = 2,6-(i)Pr(2)C(6)H(3)) has been demonstrated to be of sufficient Lewis basicity to stabilize main group hydrides in unusually low oxidation states.

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