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. 2009 Aug 22;65(Pt 9):m1110-1.
doi: 10.1107/S1600536809032553.

Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}(4-hydroxy-benzoato)manganese(III)

R Reshma, P V Soumya, S M Simi, V S Thampidas, Robert D Pike

Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}(4-hydroxy-benzoato)manganese(III)

R Reshma et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Mn(C(18)H(18)N(2)O(4))(C(7)H(5)O(3))(H(2)O)], was synthesized by a template reaction of ethane-1,2-diamine and 3-methoxy-salicylaldehyde in presence of manganese(II) 4-hydroxy-benzoate. The Jahn-Teller-distorted manganese(III) centre has an octa-hedral geometry. Extensive O-H⋯O hydrogen-bonding inter-actions generate a two-dimensional sheet structure parallel to (103).

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Figures

Fig. 1.
Fig. 1.
ORTEP picture (Farrugia, 1997) of the title compound. Displacement ellipsoids have been drawn at the 50% probability level.
Fig. 2.
Fig. 2.
Mercury capped-stick packing diagram (Macrae et al., 2006) of the title compound showing hydrogen-bonding chains and the 2-dimensional sheet structure.
See this image and copyright information in PMC

References

    1. Bermejo, M. R., Fernández, M. I., González-Noya, A. M., Maneiro, M., Pedrido, R., Rodríguez, M. J., García-Monteagudo, J. C. & Donnadieu, B. (2006). J. Inorg. Biochem.9, 1470–1478. - PubMed
    1. Bruker (2004). APEX2 and SAINT-Plus Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Christou, G. (2005). Polyhedron, 24, 2065–2075.
    1. Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
    1. Hulme, C. E., Watkinson, M., Haynes, M., Pritchard, R. G., McAuliff, C. A., Jaiboon, N., Beagley, B., Sousa, A., Bermejo, M. R. & Fondo, M. (1997). J. Chem. Soc. Dalton Trans. pp. 1805–1814.