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. 2009 Aug 8;65(Pt 9):o2086.
doi: 10.1107/S1600536809030219.

(E)-3-Bromo-N'-(4-methoxy-benzyl-idene)benzohydrazide methanol solvate

Affiliations

(E)-3-Bromo-N'-(4-methoxy-benzyl-idene)benzohydrazide methanol solvate

Guo-Biao Cao. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(15)H(13)BrN(2)O(2)·CH(3)OH, was synthesized by the reaction of 4-methoxy-benzaldehyde with an equimolar quantity of 3-bromo-benzohydrazide in methanol. The benzohydrazide mol-ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.0 (2)°. The benzohydrazide and methanol mol-ecules are linked into a chain propagating along the b axis by O-H⋯O, O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
The asymmetric unit of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
The crystal packing of the title compound, viewed along the c axis. Hydrogen bonds are shown as dashed lines. C-bound H atoms have been omitted for clarity.

References

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    1. Cao, G.-B. (2009). Acta Cryst. E65, o2085. - PMC - PubMed
    1. Cao, G.-B. & Lu, X.-H. (2009a). Acta Cryst. E65, o1587. - PMC - PubMed
    1. Cao, G.-B. & Lu, X.-H. (2009b). Acta Cryst. E65, o1600. - PMC - PubMed