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. 2009 Aug 8;65(Pt 9):o2087.
doi: 10.1107/S1600536809030256.

4-(Benzyl-ideneamino)benzene-sulfonamide

Affiliations

4-(Benzyl-ideneamino)benzene-sulfonamide

Bradley T Loughrey et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(13)H(12)N(2)O(2)S, formed by Schiff base condensation of benzaldehyde with sulfanilamide, crystallizes as discrete mol-ecular species linked by N-H⋯N and N-H⋯O hydrogen bonds between the sulfamide nitro-gen H atoms and the aza-methine N and one sulfamide O atom, respectively, forming a two-dimensional array in the bc plane. The aza-methine group is rotated slightly out of the benzaldehyde benzene plane [C-C-C-N torsion angle = 8.1 (3)°], while the dihedral angle between the two benzene rings is 30.0 (1)°.

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Figures

Fig. 1.
Fig. 1.
The structure of (I), with atom labels and 40% probability displacement ellipsoids for the non-H atoms.
Fig. 2.
Fig. 2.
Intermolecular hydrogen bonding interactions (dashed lines) for (I) leading a 2D array in the bc plane, viewed down the a axis.

References

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