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. 2009 Sep 9;65(Pt 10):m1191-2.
doi: 10.1107/S1600536809035594.

Bis(1,3-dibutylthiourea)dicyanido-mercury(II)

Saeed Ahmad, Haseeba Sadaf, Mehmet Akkurt, Shahzad Sharif, Islam Ullah Khan

Bis(1,3-dibutylthiourea)dicyanido-mercury(II)

Saeed Ahmad et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol-ecule in the asymmetric unit. The Hg atom has a distorted tetra-hedral coordination involving the S atoms of two 1-butyl-3-propyl-thio-urea groups and the C atoms of the two CN(-) anions. In the crystal packing, adjacent mol-ecules are connected by inter-molecular N-H⋯N and N-H⋯S hydrogen bonds, forming infinite chains in three dimensions.

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Figures

Fig. 1.
Fig. 1.
The title molecule with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
The packing and hydrogen bonding of (I) viewed down b axis. Hydrogen atoms not involved in the showed interactions have been omitted for clarity.
See this image and copyright information in PMC

References

    1. Ahmad, S. (2004). Coord. Chem. Rev.248, 231–243.
    1. Ahmad, S. & Isab, A. A. (2001). Inorg. Chem. Commun.4, 362–364.
    1. Ahmad, S., Isab, A. A. & Ashraf, W. (2002). Inorg. Chem. Commun.5, 816–819.
    1. Ahmad, S., Isab, A. A. & Perzanowski, H. P. (2002). Can. J. Chem.80, 1279–1283.
    1. Ashraf, W., Ahmad, S. & Isab, A. A. (2002). Transition Met. Chem.29, 400–404.