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. 2009 Sep 9;65(Pt 10):o2415.
doi: 10.1107/S1600536809035740.

(E)-4-Chloro-N'-(5-hydr-oxy-2-nitro-benzyl-idene)benzohydrazide

Affiliations

(E)-4-Chloro-N'-(5-hydr-oxy-2-nitro-benzyl-idene)benzohydrazide

Guo-Biao Cao. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(14)H(10)ClN(3)O(4), was synthesized by the reaction of 5-hydr-oxy-2-nitro-benzaldehyde with an equimolar quantity of 4-chloro-benzohydrazide in methanol. The mol-ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 3.9 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, forming chains running along the b axis.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with ellipsoids drawn at the 30% probability level.
Fig. 2.
Fig. 2.
The molecular packing of the title compound, viewed along the a axis. Hydrogen bonds are drawn as dashed lines.

References

    1. Bruker (2001). SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2007). SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cao, G.-B. (2009a). Acta Cryst. E65, o2085. - PMC - PubMed
    1. Cao, G.-B. (2009b). Acta Cryst. E65, o2086. - PMC - PubMed
    1. Cao, G.-B. & Lu, X.-H. (2009a). Acta Cryst. E65, o1587. - PMC - PubMed