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. 2009 Oct 7;65(Pt 11):m1317.
doi: 10.1107/S1600536809039920.

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II)

Yu Qing Wang  1 , Lin Meng, Jing Min Shi
Affiliations

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(thio-cyanato-κN)cadmium(II)

Yu Qing Wang et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π-π stacking inter-action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid-centroid distance of 3.578 (3) Å.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of title compound with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
See this image and copyright information in PMC

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