Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Oct 7;65(Pt 11):m1321-2.
doi: 10.1107/S1600536809039816.

Carbon-yl[4-(2,3-dimethyl-phenyl-amino)pent-3-en-2-onato-κN,O](triphenyl-phosphine-κP)rhodium(I)

Gertruida J S Venter  1 , Gideon Steyl, Andreas Roodt
Affiliations

Carbon-yl[4-(2,3-dimethyl-phenyl-amino)pent-3-en-2-onato-κN,O](triphenyl-phosphine-κP)rhodium(I)

Gertruida J S Venter et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)], the coordination geometry of the Rh(I) atom is square-planar, formed by the coordinating N and O atoms of the bidentate enaminoketonate ligand, one C atom from the carbonyl group and a P atom from triphenyl-phosphine. The complex displays a 0.591 (3):0.409 (3) ratio disorder of the phenyl unit of the monoanionic N,O-bidentate ligand. Intra-molecular hydrogen bonding is observed between a C-H group of the triphenyl-phosphine unit and the O atom of the enamino-ketonate ligand.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. H atoms have been omitted for clarity.
Fig. 2.
Fig. 2.
Crystal packing of the title compound.
See this image and copyright information in PMC

References

    1. Altomare, A., Cascarano, G., Giacovazzo, C., Guagliardi, A., Burla, M. C., Polidori, G. & Camalli, M. (1994). J. Appl. Cryst.27, 435.
    1. Bonati, F. & Wilkinson, G. (1964). J. Chem. Soc. pp. 3156–3160.
    1. Brandenburg, K. & Putz, H. (1999). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Bruker (2001). SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2007). APEX2 and SAINT-Plus Bruker AXS Inc., Madison, Wisconsin, USA.