Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Oct 23;65(Pt 11):o2820.
doi: 10.1107/S1600536809040057.

4-Bromo-N-phenyl-benzamidoxime

Mihaela Cibian  1 , Janaina G Ferreira, Garry S Hanan
Affiliations

4-Bromo-N-phenyl-benzamidoxime

Mihaela Cibian et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(13)H(11)BrN(2)O, a hydroxy-amidine derivative (an amidoxime), was obtained by addition of the corresponding imidoyl chloride to hydroxy-lamine. The benzene and phenyl rings are twisted from the mean plane of the hydroxy-amidine group by 34.4 (1) and 59.2 (1)°, respectively. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link pairs of mol-ecules, forming centrosymmetric dimers.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound (50% probability displacement ellipsoids).
Fig. 2.
Fig. 2.
A pair of molecules linked through intermolecular N—H···O bonds [Symmetry code: (i)1 - x,1 - y, 2 - z]. Hydrogen bonds are shown as dashed lines.
See this image and copyright information in PMC

References

    1. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans 2, pp. S1–19.
    1. Briggs, L. H., Cambie, R. C., Dean, C. & Rutledge, P. S. (1976). Aust. J. Chem.29, 357–366.
    1. Bruker (2009). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Deb, M. K., Mishra, N., Patel, K. S. & Mishra, R. K. (1991). Analyst, 116, 332–335.
    1. Dondoni, A., Barbaro, G. & Battaglia, A. (1977). J. Org. Chem.42, 3372–3377.