(5-Ethenyl-1-aza-bicyclo-[2.2.2]octan-2-yl)(6-meth-oxy-3-quinol-yl)methanol methanol solvate

Abstract

In the title methanol solvate, C(20)H(24)N(2)O(2)·CH(4)O, an L-shaped conformation is found as the two substituents at the central hydr-oxy group are almost orthogonal to each other [the C-C-C angle at the central sp(3)-C atom is 110.12 (13)°]. The most notable feature of the crystal packing is the formation of supra-molecular chains along the b direction mediated by O-H⋯N hydrogen bonds occurring between the hydr-oxy and quinoline N atoms; the methanol mol-ecules are linked to these chains via O-H⋯N(amine) hydrogen bonds. C-H⋯O inter-actions also occur.

Fig. 1.

Molecular structure of the asymmetric unit in (I) showing atom-labelling scheme and displacement ellipsoids at the 50% probability level. The O—H···N hydrogen bond is shown as a dashed line.

Fig. 2.

Supramolecular chain in (I) mediated by O–H···N hydrogen bonds (orange dashed lines). Methanol molecules are associated with this chain via O–H···N hydrogen bonds (black dashed lines).