Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Nov 21;65(Pt 12):m1646.
doi: 10.1107/S160053680904906X.

[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I)

Primjira P Tadbuppa, Edward R T Tiekink

[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I)

Primjira P Tadbuppa et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å].

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of (I) showing displacement ellipsoids at the 50% probability level.
See this image and copyright information in PMC

References

    1. Beurskens, P. T., Admiraal, G., Beurskens, G., Bosman, W. P., Garcia-Granda, S., Gould, R. O., Smits, J. M. M. & Smykalla, C. (1992). The DIRDIF Program System. Technical Report. Crystallography Laboratory, University of Nijmegen, The Netherlands.
    1. Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
    1. Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Hall, V. J., Siasios, G. & Tiekink, E. R. T. (1993). Aust. J. Chem. 46, 561–570.
    1. Ho, S. Y., Cheng, E. C.-C., Tiekink, E. R. T. & Yam, V. W.-W. (2006). Inorg. Chem. 45, 8165–8174. - PubMed