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. 2010 Apr 24;66(Pt 5):m570.
doi: 10.1107/S1600536810014443.

Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}methyl-tin(IV)

Md Abdus Salam, Md Abu Affan, Mustaffa Shamsuddin, Seik Weng Ng

Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}methyl-tin(IV)

Md Abdus Salam et al. Acta Crystallogr Sect E Struct Rep Online. .

Erratum in

  • Acta Crystallogr Sect E Struct Rep Online. 2010;67(Pt 1):e11

Abstract

The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].

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Figures

Fig. 1.
Fig. 1.
Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl2(CH3)(C14H19N4S) at the 50% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

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