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. 2010 Apr 17;66(Pt 5):o1102.
doi: 10.1107/S1600536810013589.

N-[Bis(dimethyl-amino)phosphinoyl]-2,2,2-trichloro-acetamide

Affiliations

N-[Bis(dimethyl-amino)phosphinoyl]-2,2,2-trichloro-acetamide

Oleksiy V Amirkhanov et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(6)H(13)Cl(3)N(3)O(2)P or CCl(3)C(O)NHP(O)(N(CH(3))(2)), the phosphinoyl group is synclinal to the carbonyl group and acts as an acceptor for an inter-molecular N-H⋯O hydrogen bond from the amide group as the donor.

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Figures

Fig. 1.
Fig. 1.
Structural representation of 1 with atom numbering scheme and 50% probability thermal ellipsoid. The hydrogen atoms are omitted for clarity.
Fig. 2.
Fig. 2.
A projection of packing diagram of the title compound along the y direction. Hydrogen bonds are indicated by dashed lines. H and Cl atoms are omitted for clarity.

References

    1. Adams, L. A., Cox, R. J., Gibson, J. S., Mayo-Martín, M. B., Walter, M. & Whittingham, W. (2002). Chem. Commun. pp. 2004–2005. - PubMed
    1. Coppens, P., Leiserowitz, L. & Rabinovich, D. (1965). Acta Cryst.18, 1035–1038.
    1. Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
    1. Farrugia, L. J. (1999). J. Appl. Cryst.32, 837–838.
    1. Gholivand, K., Alizadehgan, A., Mojahed, F. & Soleimani, P. (2008a). Polyhedron, 27, 1639–1649.

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