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. 2010 May 19;66(Pt 6):m675.
doi: 10.1107/S1600536810017861.

[2,6-Bis(di-tert-butyl-phosphinometh-yl)phenyl-κP,C,P'](trifluoro-acetato)palladium(II)

Magnus T Johnson, Mario Cetina, Kari Rissanen, Ola F Wendt

[2,6-Bis(di-tert-butyl-phosphinometh-yl)phenyl-κP,C,P'](trifluoro-acetato)palladium(II)

Magnus T Johnson et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Pd(II) atom in the title compound, [Pd(C(2)F(3)O(2))(C(24)H(43)P(2))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intra-molecular C-H⋯O hydrogen bonds occur. The crystal packing reveals one weak inter-molecular C-H⋯O hydrogen bond, which self-assembles the mol-ecules into infinite chains parallel to the b axis.

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Figures

Fig. 1.
Fig. 1.
A molecular structure of (I), with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30 % probability level. Intramolecular hydrogen bonds are shown by dashed lines.
Fig. 2.
Fig. 2.
A crystal packing diagram of (I), viewed down the c axis, showing hydrogen-bonded chains of molecules running parallel to the b axis. Hydrogen bonds are indicated by dashed lines.
See this image and copyright information in PMC

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