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. 2010 May 22;66(Pt 6):m684-5.
doi: 10.1107/S1600536810017794.

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](2,2'-bipyridine)manganese(II)

Affiliations

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](2,2'-bipyridine)manganese(II)

Tian-Jing He et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Mn(C(10)H(9)N(4)O(2)S)(2)(C(10)H(8)N(2))], contains a distorted octa-hedral [Mn(sdz)(2)(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2'-bipyridine) complex mol-ecule. A three-dimensional network is generated by N-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds from the sulfadiazine ligands.

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Figures

Fig. 1.
Fig. 1.
The molecular structure, showing the atom-labelling scheme. Displacement ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
A packing plot of the title compound view along [001]. Hydrogen bonds are shown in the dashed line, and the H atoms that are not involved in hydrogen bonding are omitted.

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