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. 2010 May 12;66(Pt 6):o1315.
doi: 10.1107/S1600536810016612.

6-De-oxy-6-fluoro-d-galactose

Sarah F Jenkinson, Daniel Best, Ken Izumori, Francis X Wilson, Alexander C Weymouth-Wilson, George W J Fleet, Amber L Thompson

6-De-oxy-6-fluoro-d-galactose

Sarah F Jenkinson et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(11)FO(5). The absolute stereochemistry was determined by the use of d-galactose as the starting material. The compound exists as a three-dimensional O-H⋯O hydrogen-bonded network with each mol-ecule acting as a donor and acceptor for four hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
Synthetic Scheme.
Fig. 2.
Fig. 2.
The title compound with displacement ellipsoids drawn at the 50% probability level. H atoms are shown as spheres of arbitrary radius.
Fig. 3.
Fig. 3.
Packing diagram of the title compound projected along the b-axis. Hydrogen bonds are shown by dotted lines.
Fig. 4.
Fig. 4.
Packing diagram of the title compound projected along the a-axis. Hydrogen bonds are shown by dotted lines.
See this image and copyright information in PMC

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