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. 2010 Jan 9;66(Pt 2):m113.
doi: 10.1107/S1600536809053999.

catena-Poly[[[diaqua-sodium]-di-μ-aqua] 2-(2-pyrid-yl)quinoline-4-carboxyl-ate]

Hu-Jun Hao, Cui-Wu Lin, Xian-Hong Yin, Fei-Long Hu, Yue Zhuang

catena-Poly[[[diaqua-sodium]-di-μ-aqua] 2-(2-pyrid-yl)quinoline-4-carboxyl-ate]

Hu-Jun Hao et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Na(H(2)O)(4)](C(15)H(9)N(2)O(2)), the Na(+) ion is coordinated by six water mol-ecules in an octa-hedral geometry. The NaO(6) octa-hedra are connected by sharing edges, forming a cationic chain along the b-axis direction. O-H⋯O and O-H⋯N hydrogen bonds link the chains and the 2-(2-pyrid-yl)quinoline-4-carboxyl-ate anions into a two-dimensional network parallel to (100).

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Figures

Fig. 1.
Fig. 1.
The structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. [Symmetry codes: (i) 1 - x, 1 - y, 1 - z; (ii) 1 - x, 2 - y, 1 - z.]
Fig. 2.
Fig. 2.
The chain of NaO6 octahedra along the b axis. [Symmetry codes: (i) 1 - x, 1 - y, 1 - z; (ii) 1 - x, 2 - y, 1 - z.]
Fig. 3.
Fig. 3.
Crystal packing of the title compound viewed along the b axis. Dashed lines indicate hydrongen bonds.
See this image and copyright information in PMC

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