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. 2010 Jan 9;66(Pt 2):m129.
doi: 10.1107/S1600536809055639.

Bis(pyridine-κN){N,N-[1,1'-(pyridine-2,6-di-yl)diethyl-idyne]benzene-sulfono-hydrazonato-κO,N,N',N'',O'}nickel(II)

Juahir Yusnita, Hapipah Mohd Ali, Mahmood A Abdulla, Ward T Robinson, Hamid Khaledi

Bis(pyridine-κN){N,N-[1,1'-(pyridine-2,6-di-yl)diethyl-idyne]benzene-sulfono-hydrazonato-κO,N,N',N'',O'}nickel(II)

Juahir Yusnita et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the crystal structure of the title compound, [Ni(C(21)H(19)N(5)O(4)S(2))(C(5)H(5)N)(2)], the metal center is seven-coordinate, with an approximate penta-gonal-bipyramidal configuration. The Ni atom is chelated by a dianionic penta-dentate Schiff base via the pyridine N atom, the two azomethine N atoms and the two sulfonyl O atoms. The latter coordinate to Ni at different distances, viz. 2.3337 (12) and 2.7988 (12) Å. Two apically coordinated pyridine mol-ecules complete the seven-coordin-ate geometry. The dihedral angle between the two pyridine ring planes is 68.25 (6)°.

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Figures

Fig. 1.
Fig. 1.
Thermal ellipsoid plot of the title compound at the 40% probability level. Hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

References

    1. Barbour, L. J. (2001). J. Supramol. Chem 1, 189–191.
    1. Bruker (2007). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Sheldrick, G. M. (1996). SADABS University of Göttingen, Germany.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
    1. Westrip, S. P. (2010). publCIF In preparation.