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. 2010 Jan 16;66(Pt 2):o384-5.
doi: 10.1107/S160053681000142X.

[3-(Iodo-acetamido)prop-yl]triphenyl-phospho-nium tetra-phenyl-borate

Cameron Evans  1
Affiliations

[3-(Iodo-acetamido)prop-yl]triphenyl-phospho-nium tetra-phenyl-borate

Cameron Evans. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(23)H(24)INOP(+)·C(24)H(20)B(-), was prepared by treatment of 3-amino-propyl triphenyl-phospho-nium bromide hydrogen bromide with p-nitro-phenyl iodo-acetate at 203 K. The asymmetric unit contains a single cation and anion, which are linked in the crystal by inter-molecular N-H⋯π and inversion-related R(2) (2)(14) C-H⋯O inter-actions, which combine to form chains of cations and anions along the c axis.

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Figures

Fig. 1.
Fig. 1.
View of the two ions in the asymmetric unit showing the atom-labelling scheme. Ellipsoids are drawn at the 50% probability level with H atoms represented by circles of arbitrary size.
Fig. 2.
Fig. 2.
View along the c axis indicating the N···π and C—H···O R22(14) hydrogen bonding network in the crystal. Hydrogen bonds and the N—H···π interactions are drawn as dotted lines. Black spheres represent the centroids of the C61—C66 rings.
See this image and copyright information in PMC

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