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. 2009 Dec 9;66(Pt 1):m28.
doi: 10.1107/S1600536809052192.

Di-μ-methoxido-μ-oxido-bis-[triphenyl-antimony(V)] methanol disolvate

Richard Betz  1 , Sebastian Junggeburth, Peter Klüfers, Peter Mayer
Affiliations

Di-μ-methoxido-μ-oxido-bis-[triphenyl-antimony(V)] methanol disolvate

Richard Betz et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Sb(2)(C(6)H(5))(6)(CH(3)O)(2)O]·2CH(3)OH, is the methanol disolvate of a dinuclear triphenyl-anti-mony derivative. The mol-ecule shows C(s) symmetry. The Sb-O-Sb angles cover a range from 89.65 (10)° to 102.08 (13)°. In the crystal structure, two O-H⋯O hydrogen bonds are present.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level) for non-H atoms. Symmetry code: i x, -y + 1/2, z.
Fig. 2.
Fig. 2.
Hydrogen bonds in the crystal structure of the title compound, viewed along [0 1 0]. Symmetry codes: i x + 1/2, y, -z + 1/2; ii x - 1/2, y, -z + 1/2.
See this image and copyright information in PMC

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