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. 2009 Dec 24;66(Pt 1):o219-20.
doi: 10.1107/S1600536809054129.

2-{[(4-Methoxy-phen-yl)dimethyl-silyl]meth-yl}isoindoline-1,3-dione

Ilia A Guzei  1 , Lara C Spencer, Uzma I Zakai
Affiliations

2-{[(4-Methoxy-phen-yl)dimethyl-silyl]meth-yl}isoindoline-1,3-dione

Ilia A Guzei et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the course of our studies of silicon-containing anti-cancer compounds, the title compound, C(18)H(19)NO(3)Si, was synthesized. The mol-ecular geometry including bond distances and angles involving the Si atoms are typical. Torsion angles associated with the isoindoline ring and the silyl group [C-N-C(methyl-ene)-Si = 90.5 (2) and -93.1 (2)°] indicate that there is no inter-action between the O and Si atoms despite silicon's high affinity for oxygen.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of (I). The thermal ellipsoids are shown at 50% probability level.
See this image and copyright information in PMC

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