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. 2010 Feb 17;66(Pt 3):o638.
doi: 10.1107/S1600536810005295.

{(1R,3S)-2-Benzyl-6,7-dimeth-oxy-1-phenyl-1,2,3,4-tetra-hydro-isoquinolin-3-yl}diphenyl-methanol

Tricia Naicker, Thavendran Govender, Hendrik G Kruger, Glenn E M Maguire

{(1R,3S)-2-Benzyl-6,7-dimeth-oxy-1-phenyl-1,2,3,4-tetra-hydro-isoquinolin-3-yl}diphenyl-methanol

Tricia Naicker et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(37)H(35)NO(3), a precursor to novel chiral catalysts, the N-containing six-membered ring assumes a half-chair conformation. Inter-molecular C-H⋯O hydrogen bonds link the mol-ecules in the crystal structure.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Hydrogen atoms have been omitted for clarity.
Fig. 2.
Fig. 2.
The C—H···O interactions (dotted lines) in the crystal structure of the title compound along the a axis. [Symmetry codes: i) x, y, z -1 ; ii) x, y, z + 1.]
Fig. 3.
Fig. 3.
Reaction scheme.
See this image and copyright information in PMC

References

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