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. 2010 Mar 3;66(Pt 4):m356.
doi: 10.1107/S1600536810007439.

Di-tert-butyl-bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')tin(IV)

Amirah Faizah Muthalib, Ibrahim Baba, Mohd Wahid Samsudin, Seik Weng Ng

Di-tert-butyl-bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')tin(IV)

Amirah Faizah Muthalib et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The dithio-carbamate anions in the title compound, [Sn(C(4)H(9))(2)(C(5)H(10)NS(2))(2)], chelate to the Sn(IV) atom, which is six-coordinated in a skew-trapezoidal-bipyramidal geometry. The mol-ecule lies across a twofold rotation axis. The crystal studied was a non-merohedral twin, the ratio of the twin components being 0.82 (1):0.18 (1).

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Figures

Fig. 1.
Fig. 1.
Displacement ellipsoid plot (Barbour, 2001) of [Sn(C6H5)2(C5H11NS2)2] at 50% probability level. H atoms are drawn as spheres of arbitrary radii. Unlabelled atoms are related to labelled atoms by the symmetry operation (3/2 - x, y, 3/2 - z).
See this image and copyright information in PMC

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