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. 2008 Oct 15;64(Pt 11):m1402.
doi: 10.1107/S1600536808032376.

[2,6-Bis(di-tert-butyl-phosphinometh-yl)-phen-yl-κP,C,P'](nitrato-κO)nickel(II)

Brian J Boro, Diane A Dickie, Eileen N Duesler, Karen I Goldberg, Richard A Kemp

[2,6-Bis(di-tert-butyl-phosphinometh-yl)-phen-yl-κP,C,P'](nitrato-κO)nickel(II)

Brian J Boro et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Ni(II) atom in the title compound, [Ni(C(24)H(43)P(2))(NO(3))], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group.

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Figures

Fig. 1.
Fig. 1.
View of the title compound showing full numbering scheme. Ellipsoids are shown at 50% probability and hydrogen atoms have been removed for clarity. Only one of the two symmetry equivalent positions for the nitrate group is shown.
Fig. 2.
Fig. 2.
Hydrogen bonding in (I). For clarity the tert-butyl substituents on P have been removed.
See this image and copyright information in PMC

References

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