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. 2008 Oct 18;64(Pt 11):m1435.
doi: 10.1107/S1600536808033151.

{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(trifluoro-methane-sulfanato-κO)copper(II)

Simon J Coles, Abdurrahman Sengul, Ozgur Kurt, Safinaz Altin

{N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N'',N'''}bis-(trifluoro-methane-sulfanato-κO)copper(II)

Simon J Coles et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra-dentate Schiff base, N,N'-bis-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine. The copper centre assumes a tetra-gonally distorted pseudo-octa-hedral geometry with the O atoms of two trifluoro-methane-sulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941 (3)-2.011 (3) Å and the Cu-O distances are 2.474 (3) and 2.564 (3) Å.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound (50% probability displacement ellipsoids).
See this image and copyright information in PMC

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