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. 2008 Dec 10;65(Pt 1):m45-6.
doi: 10.1107/S1600536808041536.

Aquabis-(6-bromo-picolinato-κN,O)copper(II)

Fei-Long Hu  1 , Zhuang Yue, Mi Yan, Wei-Qiang Luo, Xian-Hong Yin
Affiliations

Aquabis-(6-bromo-picolinato-κN,O)copper(II)

Fei-Long Hu et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Cu(C(6)H(3)BrNO(2))(2)(H(2)O)], the Cu atom adopts a distorted trigonal-bipyramidal coordination arising from two N,O-bidentate ligands and a water mol-ecule, with one N atom in an axial site and the other in an equatorial site. The dihedral angle between the pyridine ring planes is 67.6 (2)°. In the crystal, O-H⋯O hydrogen bonds result in chains propagating in [100].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) showing 30% probability displacement ellipsoids for the non-hydrogen atoms.
Fig. 2.
Fig. 2.
Part of the hydrogen bonding network, the hydrogen bonded interactions are showing as dashed lines. [symmetry codes: (I) -1+x, y, z; (II) 1-x, -y, 2-z; (III) 2-x, 1-y, 1-z; (IV) x, 1+y, -1+z; (V) 1-x, 1-y, 1-z.]
See this image and copyright information in PMC

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