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. 2008 Dec 17;65(Pt 1):m96.
doi: 10.1107/S1600536808042244.

Bis(η-cyclo-hepta-trien-yl)tri-μ-hydrido-dimolybdenum(0,I)

Peter G Jones  1 , Cristian G Hrib, Sören Randoll, Xian Wu, Matthias Tamm
Affiliations

Bis(η-cyclo-hepta-trien-yl)tri-μ-hydrido-dimolybdenum(0,I)

Peter G Jones et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Mo(2)(η(7)-C(7)H(7))(2)(μ-H)(3)], which displays crystallographic mirror symmetry, two (η(7)-C(7)H(7))Mo units are linked along the Mo-Mo axis by three bridging hydride ligands. The Mo-Mo distance is 2.5732 (4) Å. The perpendicular distances of the Mo atoms from the C(7) planes are 1.5827 (8) and 1.5814 (8) Å, with individual Mo-C bond lengths in the range 2.261 (2)-2.2789 (14) Å. Mo-H distances range from 1.77 (3) to 1.85 (4) Å, with Mo-H-Mo angles of 89 (2) and 92 (1)°.

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Figures

Fig. 1.
Fig. 1.
The formula unit of the title compound in the crystal. Ellipsoids represent 50% probability levels.
See this image and copyright information in PMC

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