Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Jan 8;65(Pt 2):m134.
doi: 10.1107/S1600536808043596.

Poly[(3-nitro-benzoato)(μ(3)-1,2,4-triazolato)cobalt(II)]

Xu-Liang Qi  1
Affiliations

Poly[(3-nitro-benzoato)(μ(3)-1,2,4-triazolato)cobalt(II)]

Xu-Liang Qi. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Co(C(2)H(2)N(3))(C(7)H(4)NO(4))](n), the Co(II) atom is five-coordinated by three triazolate ligands and one bidentate 3-nitro-benzoate anion in a distorted trigonal-bipyramidal geometry. The triazolate ligand bridges the Co(II) atoms, generating a two-dimensional net parallel to the ab plane, in which both the Co(II) atom and the triazolate ligand act as three-connected nodes. Two weak inter-molecular C-H⋯O hydrogen bonds connect the nets.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
An ORTEP view of the asymmetric unit with 50% thermal ellipsoids for non-H atoms [symmetry codes: (A) -x + 1/2, y - 1/2, z; (B) x + 1/2, -y + 3/2, -z + 1].
Fig. 2.
Fig. 2.
a) View of the two-dimensional net onto the ab plane, formed by cobalt ions and trz ligands; b) View of the two-dimensional net built on three-connected trz and cobalt nodes.
See this image and copyright information in PMC

References

    1. Bruker (2001). SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Park, H., Moureau, D. M. & Parise, J. B. (2006). Chem. Mater.18, 525–531.
    1. Sheldrick, G. M. (2004). SADABS University of Göttingen, Germany.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
    1. Yang, E.-C., Liu, Z.-Y., Wang, X.-G., Batten, S. R. & Zhao, X.-J. (2008). CrystEngComm, 10, 1140–1143.