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. 2009 Feb 25;65(Pt 3):i21.
doi: 10.1107/S160053680900631X.

Li(3)Al(MoO(2))(2)O(2)(AsO(4))(2)

Mounir Hajji  1 , Mohamed Faouzi Zid, Ahmed Driss
Affiliations

Li(3)Al(MoO(2))(2)O(2)(AsO(4))(2)

Mounir Hajji et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Single crystals of trilithium(I) aluminium(III) bis-[dioxidomolybdenum(VI)] dioxide bis-[arsenate(V)], Li(3)AlMo(2)As(2)O(14), have been prepared by solid-state reaction at 788 K. The structure consists of AsO(4) tetra-hedra, AlO(6) octa-hedra and Mo(2)O(10) groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li(+) ions are located. This structure is compared with compounds having (MX(2)O(12))(n) chains (M = Mo, Al and X = P, As) and others containing M(2)O(10) (M = Mo, Fe) dimers.

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Figures

Fig. 1.
Fig. 1.
Unité structurale dans Li3AlMo2As2O14. Les ellipsoïdes d'agitation thermique ont 50% de probabilité. [Codes de symétrie: (i) x, y + 1, z; (ii) -x + 1, -y + 1, -z + 1; (iii) -x + 1, -y + 2, -z + 1; (iv) x - 1, y, z; (v) -x + 1, -y, -z; (vi) x, y - 1, z; (vii) -x + 1, -y + 1, -z.]
Fig. 2.
Fig. 2.
Projection de la structure de Li3AlMo2As2O14 selon a montrant les deux types de canaux où logent les cations Li+.
Fig. 3.
Fig. 3.
Projection de la structure de Li3AlMo2As2O14 selon b montrant les larges canaux où résident les cations Li+.
See this image and copyright information in PMC

References

    1. Borel, M. M., Guesdon, A., Leclaire, A., Grandin, A. & Raveau, B. (1994). Z. Anorg. Allg. Chem.620, 569–573.
    1. Brandenburg, K. (1998). DIAMOND University of Bonn, Germany.
    1. Brown, I. D. & Altermatt, D. (1985). Acta Cryst. B41, 244–247.
    1. Driss, A. & Jouini, T. (1989). Acta Cryst. C45, 356–360.
    1. Duisenberg, A. J. M. (1992). J. Appl. Cryst.25, 92–96.