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. 2009 Mar 19;65(Pt 4):m418.
doi: 10.1107/S1600536809009234.

{4-Bromo-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato}iodido(methanol)zinc(II)

Cheng-Li Han  1
Affiliations

{4-Bromo-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato}iodido(methanol)zinc(II)

Cheng-Li Han. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Zn(C(13)H(16)BrN(2)O(2))I(CH(3)OH)], is a new mononuclear zinc(II) complex synthesized by the reaction of equimolar quanti-ties of 5-bromo-salicylaldehyde, 2-morpholinoethyl-amine and ZnI(2) in methanol. The Zn atom is four-coordinate in a distorted tetra-hedral geometry, binding to a phenolate O and an imine N atom of the Schiff base ligand, the O atom of a methanol mol-ecule and one I(-) anion. In the crystal structure, adjacent mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds, forming centrosymmetric dimers.

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Figures

Fig. 1.
Fig. 1.
The structure of the complex, showing 30% probability displacement ellipsoids and the atom-numbering scheme.
Fig. 2.
Fig. 2.
The crystal packing of (I) showing the formation of centrosymmetric dimers. Hydrogen bonds are shown as dashed lines.
See this image and copyright information in PMC

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