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. 2009 Mar 25;65(Pt 4):o821-2.
doi: 10.1107/S1600536809009751.

(E)-N'-(4-Bromo-benzyl-idene)-p-toluene-sulfonohydrazide

Reza Kia, Bijan Etemadi, Hoong-Kun Fun, Hadi Kargar

(E)-N'-(4-Bromo-benzyl-idene)-p-toluene-sulfonohydrazide

Reza Kia et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link neighbouring mol-ecules into different dimers along the b axis, generating R(2) (2)(8) and R(2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82.39 (13)°. The crystal structure is further stabilized by inter-molecular π-π stacking inter-actions [centroid-centroid distances = 3.867 (2)-3.9548 (8) Å].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, showing 50% probability displacement ellipsoids and the atomic numbering.
Fig. 2.
Fig. 2.
The crystal packing of the title compound, viewed down the a axis, showing linking of different dimers along the b axis through N—H···O and C—H···O interactions. Intermolecular hydrogen bonds are shown as dashed lines.
See this image and copyright information in PMC

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