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2-Acetyl-pyridinium bromanilate

Lynne H Thomas et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the crystal of the title mol-ecular salt (systematic name: 2-acetyl-pyridinium 2,5-dibromo-4-hydr-oxy-3,6-dioxocyclo-hexa-1,4-dienolate), C(7)H(8)NO(+)·C(6)HBr(2)O(4) (-), centrosymmetric rings consisting of two cations and two anions are formed, with the components linked by alternating O-H⋯O and N-H⋯O hydrogen bonds. Short O⋯Br contacts [3.243 (2) and 3.359 (2) Å] may help to consolidate the packing.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) with displacement ellipsoids drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The hydrogen bonded ring between alternating bromanilic acid and acetylpyridine molecules. The hydrogen bonds are indicated by dashed lines. The * indicates the atoms are related by the symmetry code 2 - x, 1 - y, 1 - z.
Fig. 3.
Fig. 3.
The short bromine-oxygen close contacts connecting the hydrogen bonded rings. The short contacts and hydrogen bonds are indicated by dashed lines.
See this image and copyright information in PMC

References

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