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. 2009 Jul 11;65(Pt 8):m889.
doi: 10.1107/S1600536809025641.

Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II))

Ali Mahmoudi, Saeed Dehghanpour, Mehdi Khalaj, Shabnam Pakravan

Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II))

Ali Mahmoudi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

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Figures

Fig. 1.
Fig. 1.
The molecular structure od the title complex, with displacement ellipsoids drawn at the 50% probability level. H atoms are represented as spheres of arbitrary radius [symmetry code: (a) -x, -y+1, -z].
See this image and copyright information in PMC

References

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    1. Dehghanpour, S., Mahmoudi, A., Khalaj, M. & Salmanpour, S. (2007). Acta Cryst. E63, m2840.
    1. Dehghanpour, S., Mahmoudi, A., Khalaj, M., Salmanpour, S. & Adib, M. (2007). Acta Cryst. E63, m2841.
    1. Mahmoudi, A., Khalaj, M., Gao, S., Ng, S. W. & Mohammadgholiha, M. (2009). Acta Cryst. E65, m555. - PMC - PubMed