Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Jul 22;65(Pt 8):m964.
doi: 10.1107/S1600536809028220.

Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}zinc(II)

Amitabha Datta  1 , Nien-Tsu Chuang, Jui-Hsien Huang, Hon Man Lee
Affiliations

Dichlorido{2-[2-(dimethyl-ammonio)ethyl-imino-meth-yl]-6-methoxy-phenolato}zinc(II)

Amitabha Datta et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra-hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter-molecular N-H⋯O and C-H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to the c-glide planes.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The structure of the title complex, showing 50% displacement ellipsoids for non-H atoms. The H atoms are depicted by circles of arbitrary radius.
Fig. 2.
Fig. 2.
A packing diagram of the title compound showing the intermolecular hydrogen bonds (dashed lines).
See this image and copyright information in PMC

References

    1. Bruker (2004). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Qiu, X.-Y. (2006). Acta Cryst. E62, m2173–m2174.
    1. Sheldrick, G. M. (2003). SADABS University of Göttingen, Germany.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
    1. Wang, Q. & Qiu, X.-Y. (2006). Acta Cryst. E62, m3002–m3003.