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. 2009 Jul 25;65(Pt 8):m996.
doi: 10.1107/S1600536809029006.

Bis[N'-(2-pyridylmethyl-ene-κN)benzo-hydrazide-κN']bis-(thio-cyanato-κN)cobalt(II)

Amitabha Datta  1 , Nien-Tsu Chuang, Jui-Hsien Huang, Hon Man Lee
Affiliations

Bis[N'-(2-pyridylmethyl-ene-κN)benzo-hydrazide-κN']bis-(thio-cyanato-κN)cobalt(II)

Amitabha Datta et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa-hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio-cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on a crystallographic twofold rotational axis. Non-classical inter-molecular C-H⋯O hydrogen bonds link the complex mol-ecules into chains along [001].

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Figures

Fig. 1.
Fig. 1.
The structure of the title complex, showing 50% displacement ellipsoids for non-H atoms. The H atoms are dipicted by circles of an arbitrary radius. Unlabeled atoms of the complex are related to the labeled atoms by: -x, y, 0.5 - z.
Fig. 2.
Fig. 2.
A packing diagram of the title compound along the a axis showing the intermolecular hydrogen bonds (dashed lines).
See this image and copyright information in PMC

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