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. 2009 Jul 29;65(Pt 8):o2012.
doi: 10.1107/S1600536809028980.

(2R,4R)-2-Hydr-oxy-4-(2-methoxy-phen-yl)bicyclo-[3.3.1]nonan-9-one

Shuping Luo  1 , Guangcun Zhang, Shuai Zhang, Yifeng Wang, Wei Zhang
Affiliations

(2R,4R)-2-Hydr-oxy-4-(2-methoxy-phen-yl)bicyclo-[3.3.1]nonan-9-one

Shuping Luo et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(16)H(20)O(3), contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonds. The absolute configuration was established by the stereo-selectivity of the asymmetric organocatalysis.

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Figures

Fig. 1.
Fig. 1.
Thermal ellipsoid representation of the of title compound with the atomic labeling scheme. Displacement ellipsoids are drawn at the 40% probability level.
Fig. 2.
Fig. 2.
View of the hydrogen bonding interactions. H bonds are represented as dashed lines. Symmetery codes: (i) x + 1/2, -y - 1/2, -z. (iv) -x, y + 1/2, 1/2 -z. (v) 1/2 - x, -y - 1, - 1/2 + z.
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