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. 2009 Apr 10;65(Pt 5):m507.
doi: 10.1107/S1600536809012975.

Poly[μ(2)-chlorido-(μ(2)-3H-1,3,4-thia-diazo-lium-2-thiol-ato-κS:S)silver(I)]

Jian-Ge Wang  1 , Jian-Hua Qin, Pu-Zhou Hu
Affiliations

Poly[μ(2)-chlorido-(μ(2)-3H-1,3,4-thia-diazo-lium-2-thiol-ato-κS:S)silver(I)]

Jian-Ge Wang et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [AgCl(C(2)H(2)N(2)S(2))](n), the Ag(I) ion has a distorted tetra-hedral geometry, defined by two S atoms of two symmetry-related 1,3,4-thia-diazo-lium-2-thiol-ate ligands and two chloride ions. The Ag(I) ions are bridged into a two-dimensional network parallel to the ab plane by chloride ions and thia-diazole ligands. In the network, the Ag(I) ions are separated by 4.0316 (12) Å along the a axis and by 4.8822 (13) Å along the b axis. N-H⋯Cl hydrogen bonds are observed within the network.

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Figures

Fig. 1.
Fig. 1.
A view of the local coordination of the AgI atom in the title compound. Displacement ellipsoids are drawn at the 30% probability level. Symmetry codes: (A) 2 -x, y - 1/2, 1/2 - z; (B) x - 1, y, z.
Fig. 2.
Fig. 2.
A view of the two-dimensional network parallel to the ab plane.
See this image and copyright information in PMC

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