Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2009 Apr 25;65(Pt 5):m558-9.
doi: 10.1107/S1600536809014329.

Tricarbonyl(chlorodiphenylstannyl){η-[2-(dimethylamino)ethyl]cyclopenta-dienyl}molybdenum

Paul J Fischer, Kristina M Krohn, Victor G Young Jr

Tricarbonyl(chlorodiphenylstannyl){η-[2-(dimethylamino)ethyl]cyclopenta-dienyl}molybdenum

Paul J Fischer et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Reaction of the tricarbon-yl{η(5)-[2-(dimethyl-amino)eth-yl]cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo-Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of 1 (50% thermal ellipsoids).
See this image and copyright information in PMC

References

    1. Braunschweig, H., Bera, H., Geibel, B., Dörfler, R., Götz, D., Seeler, F., Kupfer, T. & Radacki, K. (2007). Eur. J. Inorg. Chem. pp. 3416–3424.
    1. Braunschweig, H., Dörfler, R., Mager, J., Radacki, K. & Seeler, F. (2009). J. Organomet. Chem.694, 1134–1137.
    1. Bruker (2003). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Fischer, P. J., Krohn, K. M., Mwenda, E. T. & Young, V. G. Jr (2005). Organometallics, 24, 1776–1779.
    1. Kubácek, P., Hoffmann, R. & Havias, Z. (1982). Organometallics, 1, 180–188.