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. 2009 Apr 30;65(Pt 5):m600-1.
doi: 10.1107/S160053680901527X.

catena-Poly[[diaqua-cadmium(II)]-μ-(methyl morpholino dichloro-methylene-diphospho-nato)-κO,O':O''-[tetra-aqua-cadmium(II)]-μ-(methyl morpholino dichloro-methyl-enediphospho-nato)-κO:O',O'']

Jonna Jokiniemi, Jouko Vepsäläinen, Markku Ahlgrén

catena-Poly[[diaqua-cadmium(II)]-μ-(methyl morpholino dichloro-methylene-diphospho-nato)-κO,O':O''-[tetra-aqua-cadmium(II)]-μ-(methyl morpholino dichloro-methyl-enediphospho-nato)-κO:O',O'']

Jonna Jokiniemi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro-methyl-enediphospho-nate ligands into chains in the c-axis direction. These chains are further connected by O-H⋯O hydrogen bonds into a layer-like construction along (100).

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Figures

Fig. 1.
Fig. 1.
Structure of the title compound showing the atomic numbering scheme and 50% probability displacement ellipsoids. Hydrogen atoms are omitted for clarity. Atoms labelled with suffixes A and B are at the symmetry postitions (1 - x, y, 1/2 - z) and (1 - x, 1 - y, - z) respectively.
Fig. 2.
Fig. 2.
Packing of the title compound viewed along the b-axis. CdO6 octahedra are presented in medium grey and PO3C and NPO2C tetrahedra in dark grey. Hydrogen atoms are omitted for clarity.
See this image and copyright information in PMC

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References

    1. Brandenburg, K. (2005). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Clearfield, A. (1998). Progress in Inorganic Chemistry: Metal Phosphonate Chemistry, edited by K. D. Karlin, Vol. 47, pp. 371–510, and references therein. New York: Wiley.
    1. Clearfield, A., Krishnamohan Sharma, C. V. & Zhang, B. (2001). Chem. Mater.13, 3099–3112.
    1. Fu, R., Hu, S. & Wu, X. (2007). Cryst. Crowth. Des.7, 1134–1144.
    1. Jokiniemi, J., Peräniemi, S., Vepsäläinen, J. J. & Ahlgrén, M. (2008). CrystEngComm, 10, 1011–1017.