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. 2009 Apr 22;65(Pt 5):o1084.
doi: 10.1107/S1600536809014238.

P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide

Normen Peulecke, Bhaskar R Aluri, Anina Wöhl, Anke Spannenberg, Mohammed H Al-Hazmi

P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide

Normen Peulecke et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N-H⋯S hydrogen bonding influences the mol-ecular conformation; a P-N-P-N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound showing the labelling scheme. Atomic displacement ellipsoids are drawn at the 30% probability level.
See this image and copyright information in PMC

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