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. 2010 Sep 8;66(Pt 10):m1219.
doi: 10.1107/S1600536810035336.

Aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO]bis-(pyridine-κN)copper(II)

Guo-Qing Jiang  1 , Jian-Hua Chen, Miao Wang, Yu-Jun Shi
Affiliations

Aqua-bis-[4-(methyl-sulfan-yl)benzoato-κO]bis-(pyridine-κN)copper(II)

Guo-Qing Jiang et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title mol-ecule, [Cu(C(8)H(7)O(2)S)(2)(C(5)H(5)N)(2)(H(2)O)], the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of two 4-(methyl-sulfan-yl)benzoate anions and two N atoms of two pyridine ligands and a water O atom situated at the apical site. In the crystal structure, O-H⋯O hydrogen bonds link mol-ecules into chains along the b axis.

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Figures

Fig. 1.
Fig. 1.
View of (I) with the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
A portion of the crystal packing showing a hydrogen-bonded (dashed lones) chain.
See this image and copyright information in PMC

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