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. 2010 Sep 18;66(Pt 10):m1284.
doi: 10.1107/S1600536810036846.

Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II)

Niloufar Akbarzadeh Torbati, Ali Reza Rezvani, Nasser Safari, Hamideh Saravani, Vahid Amani

Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II)

Niloufar Akbarzadeh Torbati et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [CoCl(2)(C(12)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 6,6'-dimethyl-2,2'-bipyridine ligand and two terminal Cl atoms. Inter-molecular C-H⋯Cl hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.788 (1) and 3.957 (1) Å] are present in the crystal structure.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound. Displacement ellipsoids are drawn at the 30% probability level.
Fig. 2.
Fig. 2.
Crystal packing diagram for the title compound. Dashed lines denote hydrogen bonds.
See this image and copyright information in PMC

References

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