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. 2010 Sep 25;66(Pt 10):m1288.
doi: 10.1107/S1600536810033477.

4-(4-Pyrid-yl)pyridinium penta-aqua(pyridazine-4,5-dicarboxyl-ato)praseodymate(III)

4-(4-Pyrid-yl)pyridinium penta-aqua(pyridazine-4,5-dicarboxyl-ato)praseodymate(III)

Zhen-Qin Zhang et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, (C(10)H(9)N(2))[Pr(C(6)H(2)N(2)O(4))(2)(H(2)O)(5)], the Pr atom is nine-coordinated by nine O atoms from two pyridazine-4,5-dicarboxyl-ate anions and five water mol-ecules. It is noteworthy that there is a protonated bipyridine mol-ecule in the structure. Inter-molecular O-H⋯O, O-H⋯N and N-H⋯N hydrogen bonds are present, resulting in a three-dimensional network.

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Figures

Fig. 1.
Fig. 1.
Crystal structure and atom numbering of the title compound, shown with 20% probability displacement ellipsoids. Symmetry code for atoms labelled with A: 1-x, 1-y, z.
Fig. 2.
Fig. 2.
The packing digram of the title compound.

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