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. 2010 Jun 16;66(Pt 7):m809.
doi: 10.1107/S1600536810022300.

Hexaaqua-manganese(II) 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate monohydrate

Cheng-Jun Hao  1 , Yun-Li Cao
Affiliations

Hexaaqua-manganese(II) 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate monohydrate

Cheng-Jun Hao et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Mn(H(2)O)(6)](C(16)H(12)O(6))·H(2)O, the [Mn(H(2)O)(6)](2+) complex cation lies on a mirror plane, the 4,4'-(1,2-dihy-droxy-ethane-1,2-di-yl)dibenzoate anion is located on an inversion center and the solvent water mol-ecule also lies on a mirror plane. Extensive O-H⋯O hydrogen-bonding inter-actions between the cations, anions and water mol-ecules stabilize the three-dimensional network.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound. Displacement ellipsoids are shown at the 30% probability level. H atoms and water molecule are omitted for clarity. [Symmetry codes: (i) 1-x, 1-y, 1-z; (ii) x, 3/2-y, z.]
Fig. 2.
Fig. 2.
View of the three-dimensional network constructed by O—H···O hydrogen bonds (dashed lines). H atoms are omitted for clarity.
See this image and copyright information in PMC

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