3,4-Dimeth-oxy-benzaldehyde [2,8-bis-(trifluoro-meth-yl)quinolin-4-yl]hydrazone
- PMID: 21587959
- PMCID: PMC3006850
- DOI: 10.1107/S1600536810021616
3,4-Dimeth-oxy-benzaldehyde [2,8-bis-(trifluoro-meth-yl)quinolin-4-yl]hydrazone
Abstract
In the title compound, C(20)H(15)F(6)N(3)O(2), the quinoline ring system is almost coplanar with the benzene ring; the dihedral angle between the two planes is 2.31 (8)°. The crystal structure displays an inter-molecular C-H⋯F hydrogen bond. In addition, a weak π-π inter-action is observed between the unfused benzene ring and the benzene ring of quinoline, with a centroid-centroid distance of 3.586 (1) Å.
Figures
References
-
- Andries, K., Verhasselt, P., Guillemont, J., Gohlmann, H. W., Neefs, J. M., Winkler, H., Van Gestel, J., Timmerman, P., Zhu, M., Lee, E., Williams, P., de Chaffoy, D., Huitric, E., Hoffner, S., Cambau, E., Truffot-Pernot, C., Lounis, N. & Jarlier, V. (2005). Science, 307, 223–227. - PubMed
-
- Bruker (2001). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
-
- Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
-
- Jayaprakash, S., Iso, Y., Wan, B., Franzblau, S. G. & Kozikowski, A. P. (2006). ChemMedChem, 1, 593–597. - PubMed