Tetra-pyridinium μ-oxido-di-μ-sulfato-bis-[chloridodioxidomolybdate(VI)]

Abstract

The title salt, (C(5)H(6)N)(4)[Mo(2)Cl(2)O(5)(SO(4))(2)], comprises four pyridinium cations for each [(MoClO(2))(2)(μ-O)(μ-SO(4))(2)](4-) anionic unit. The asymmetric unit consists of three aggregates of the empirical formula. The tetra-anionic bimetallic molybdenum(VI) cluster is unprecedented and contains two sulfate and one oxide bridges. This structure constitutes the first example of a non-polymeric compound with terminal oxide, sulfate and halide ligands bonded to the same metal. The hydrogen bonds connecting the pyridinium cations to the molybdenum clusters are diverse, varying from strong and directional interactions to bifurcated bonds with a subsequent loss of directionality.

Fig. 1.

Molecular structure of [(MoClO2)2(µ-O)(µ-SO4)2]4- (residue 1). Thermal ellipsoids are drawn at the 30% probability level. For the ranges of bond lengths (in Å) and angles (in °) of the three crystallographically independent anionic residues see Table 1.

Fig. 2.

Crystal packing of the title compound viewed in perspective along the [001] direction of the unit cell.