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. 2010 Jul 24;66(Pt 8):m1021.
doi: 10.1107/S1600536810028898.

(Acetyl-acetone 3-hy-droxy-2-naphtho-yl-hydrazonato-κO,N',O')(methoxo-κO)oxidovanadate(V)

Hon Wee Wong  1 , Kong Mun Lo, Seik Weng Ng
Affiliations

(Acetyl-acetone 3-hy-droxy-2-naphtho-yl-hydrazonato-κO,N',O')(methoxo-κO)oxidovanadate(V)

Hon Wee Wong et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally V(V) atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hy-droxy H atom forms an intra-molecular O-H⋯N hydrogen bond with an N-atom acceptor site.

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Figures

Fig. 1.
Fig. 1.
Displacement ellipsoid plot of VO(CH3O)(C16H14N2O3) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

References

    1. Barbour, L. J. (2001). J. Supramol. Chem.1, 189–191.
    1. Bruker (2009). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Sarkari, A. & Pal, S. (2009). Inorg. Chim. Acta, 362, 3807–3812.
    1. Shao, M.-C., Zhang, Y.-J., Zhang, Z.-Y. & Tang, Y.-Q. (1988). Sci. Chin. Ser. B (Engl. Ed.), 31, 781–788.
    1. Sheldrick, G. M. (1996). SADABS University of Göttingen, Germany.