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. 2010 Jul 24;66(Pt 8):m1022.
doi: 10.1107/S1600536810028916.

Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II)

Meng-Ling Lin, Chen-Yen Tsai, Chen-Yu Li, Bor-Hunn Huang, Bao-Tsan Ko

Bis{1-[(E)-(2-methyl-phen-yl)diazen-yl]-2-naphtho-lato}palladium(II)

Meng-Ling Lin et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Pd(C(17)H(13)N(2)O)(2)], the Pd(II) atom is tetra-coordinated by two N atoms and two O atoms from two bidentate methylphenyl-diazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the Pd(II) atom are trans to each other (as the Pd(II) atom lies on a crystallographic inversion centre) with O-Pd-N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the Pd(II) atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively.

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Figures

Fig. 1.
Fig. 1.
A view of the I with the atom numbering scheme. Displacement ellipsoids are drawn at the 30% probability level. Symmetry operator: i, -x+1/2, -y+3/2, -z+2.
See this image and copyright information in PMC

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