Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2010 Jul 31;66(Pt 8):m1042-3.
doi: 10.1107/S160053681002893X.

Tetra-ethyl-ammonium tricarbonyl-chlorido(quinoxaline-2-carboxyl-ato-κN,O)rhenate(I)

Janine Suthiram, Jan Rijn Zeevaart, Hendrik G Visser, Andreas Roodt

Tetra-ethyl-ammonium tricarbonyl-chlorido(quinoxaline-2-carboxyl-ato-κN,O)rhenate(I)

Janine Suthiram et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C-H⋯O hydrogen bonding and π-π stacking inter-actions involving the benzene rings, with a centroid-centroid distance of 3.4220 (1) Å.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability displacement level.
Fig. 2.
Fig. 2.
π-π -Stacking interactions of the title compound; cations have been omitted for clarity.
See this image and copyright information in PMC

References

    1. Alberto, R., Schibli, R. & Schubiger, P. A. (1996). Polyhedron, 15, 1079–1083.
    1. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.
    1. Altomare, A., Burla, M. C., Camalli, M., Cascarano, G. L., Giacovazzo, C., Guagliardi, A., Moliterni, A. G. G., Polidori, G. & Spagna, R. (1999). J. Appl. Cryst.32, 115–119.
    1. Alvarez, C. M., Garcia-Rodriguez, R. & Miguel, D. (2007). Dalton Trans. pp. 3546–3554. - PubMed
    1. Brandenburg, K. & Putz, H. (2005). DIAMOND Crystal Impact GbR, Bonn, Germany.