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. 2010 Jul 3;66(Pt 8):m878.
doi: 10.1107/S160053681002550X.

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(nitrito-κO,O')cadmium(II)

Jing Min Shi  1 , Lin Meng, Yu Qing Wang
Affiliations

[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(nitrito-κO,O')cadmium(II)

Jing Min Shi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Cd(NO(2))(2)(C(17)H(14)N(4))], the Cd(II) ion assumes a distorted monocapped octa-hedral coordination geometry defined by an N(3)O(4) donor set. The crystal structure is stabilized by π-π stacking inter-actions [shortest centroid-centroid distance = 3.5537 (18) Å].

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Figures

Fig. 1.
Fig. 1.
Molecular structure of (I) showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
See this image and copyright information in PMC

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